PLEIADES beamline
ASSOCIATED PUBLICATION
Single-molecule X-ray interferometry:
controlling coupled electron-nuclear quantum
dynamics and imaging molecular potentials
by ultrahigh-rsolution resonant photoemission
and ab initio calculations
V. Kimberg, A. Lindblad, J. Söderström,
O. Travnikova, C. Nicolas, Y. P. Sun,
F. Gel’mukhanov, N. Kosugi, and C. Miron*
Physical Review X 3(1) (2013) 011017
REFERENCES
[1] C. Miron et al.,
/
Recherche/LignesLumiere/PLEIADES
[2] C. Miron & P. Morin, in Handbook of High-
Resolution Spectroscopy, edited by
M. Quack and F. Merkt (Wiley, Chichester,
England, 2011), 1655
[3] C. Miron et al., Nature Phys. 8 (2012), 135
[4] P. Baltzer et al., Phys. Rev. A 46 (1992), 5545
[5] F. Gel'mukhanov & H. Ågren,
Physics Reports 1999 312, 87
*Synchrotron SOLEIL, L’Orme des Merisiers,
Saint-Aubin, BP 48, 91192 Gif-sur-Yvette
Cedex, France
CORRESPONDING AUTHOR
➋
Illustration of the PEC mapping in the framework of the high-resolution RPE spectroscopy. (
a
) Vibrational
wave functions in the core-excited state. (
b
) The reconstructed molecular potentials of the 1
2
Π
g
and 1
2
Δ
g
final ionic states (solid lines) and
ab initio
calculated potentials (open circles). The uncertainty
in the reconstructed potential curves is represented by the thickness of the lines. (
c
) The experimental RPE
spectra are presented in relation to the reconstructed PECs.
➌
(
a
) Geometric interpretation of the phenomenon of mapping of the core-excited vibrational wave
functions onto the 1
2
Π
g
bound final state based on the reflection principle. (
b
) The time-dependent dynamics
of the correspondent final state vibrational wave packets.
75
SOLEIL
HIGHLIGHTS
2013
